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P-Hydroquinone, known as hydroquinone or hydroquinone in Chinese, is an important organic compound with the chemical formula C6H6O2 and a white crystalline form. This compound has a wide range of applications in the chemical industry, the pharmaceutical field, and the photographic industry. In terms of uses, P-Hydroquinone is mainly used in the production of black and white developers, anthraquinone dyes, azo dyes and so on. In the rubber industry, it is often used as an antioxidant, which helps to extend the service life of rubber products.
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The unsaturated resin polymerization inhibitor MTBHQ (2-tert-butylhydroquinone) plays an important role in resin synthesis and other synthetic reactions. The following is a detailed analysis of its principle of action and effects:Effect Remarkable polymerization inhibition effect: MTBHQ is a kind of high efficient polymerization inhibitor for unsaturated resin. Under normal storage conditions, the general addition amount is only two ten-thousandths of the total amount of resin, and it can play a good effect of polymerization inhibition.
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1.Product Characteristics1. Synthetic oil antioxidant TBHQ is a highly efficient, low-toxicity phenolic antioxidant with excellent antioxidant effect, and the antioxidant capacity is up to 5-7 times compared with existing food antioxidants such as BHA, BHT and PG.2. Synergistic: TBHQ can be used together with other antioxidants (such as BHA, B HT) and chelating agents (such as citric acid, etc.).3. High temperature resistance: TBHQ can be used in high temperature processed food, such as frying food, with good thermal stability.4.
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According to the hygiene standard GB2760 (0.4007) for the use of food additives in the People's Republic of China, TBHQ can be used for edible oils, fried foods, dried fish products, biscuits, instant noodles, instant boiled rice, canned dried fruits, pickled meat products, roasted and fried nut foods (supplemented in February 2007), etc. The maximum usage is 0.2g/kg. It is generally recommended to use 0.01~0.02% of the total amount of oil.One dose is versatile and can effectively inhibit the growth of bacteria and molds.
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T-butylhydroquinone, abbreviated as TBHQ, has a molecular formula of Cl0H1402 and a molecular weight of 166.22. [1] It is a white to light gray crystalline or crystalline powder with a very slight special odor. It is soluble in ethanol, acetic acid, ethyl ester, isopropanol, ether, and oils, and is almost insoluble in water (25 ℃,<1%; 95 ℃, 5%). TBHQ is an oil soluble antioxidant that can prevent or delay the oxidation and deterioration of fats in food.
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More than 20 countries have approved the use of TBHQ as a food antioxidant, including China, the United States, Australia, Brazil, etc. The US Food and Drug Administration (FDA) allows TBHQ to be used alone or in combination (with BHA or BHT) for oil or fatty foods, including volatile essential oils, with a maximum allowable dosage of 200PPM. It can also be used in non-alcoholic beverages, margarine, and mixed nuts.China allows TBHQ to be used as a food additive, with a maximum dosage of 0.2g/Kg.
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Tert butyl hydroquinone (TBHQ), also known as tert butyl hydroquinone, is a white crystalline powder with a melting point of 126.5-128.5 ℃ and a boiling point of 300 ℃. Its CAS number is 1948-33-0, and it is easily soluble in ethanol and ether. It is the most effective antioxidant for most oils, especially vegetable oils. T-butylhydroquinone, abbreviated as TBHQ, has a molecular formula of Cl0H1402 and a molecular weight of 166.22. [1] It is a white to light gray crystalline or crystalline powder with a very slight special odor.
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Product ParametersSynthetic grease antioxidant TBHQ, is a white or slightly reddish-brown crystalline powder with a very light special fragrance, almost insoluble in water (about 5 per cent), soluble in organic solvents such as ethanol, ethyl acetate, ether and so on.How to use the productPumping methodSeed method of preparation of TBHQ concentrated solution, through the stainless steel quantitative pump in accordance with the prescribed ratio of injection needs to be stabilized with a fixed flow rate, flow rate of fat or oil in the pipeline.
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TBHQ may volatilize faster than BHT. Therefore, the application of microcapsule technology can solve this problem under high temperature conditions. Using natural antioxidant tea polyphenols, BHA, BHT, and synergistic agent citric acid as the core material, and food grade natural substance p-cyclodextrin as the wall material, microcapsule antioxidant was prepared using microcapsule technology.Water soluble antioxidants are soluble in water and mainly used for food oxidation and discoloration.
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Hydroquinone  Uses:In medicine, hydroquinone is mainly used in the treatment of pigmented skin diseases, such as chloasma and freckles, etc.
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Physical and chemical properties:Density: 1.328g/cm3Melting point: 172-175℃Boiling point: 286℃Flash factor: 141.6Refractive index: 1.612Vital temperature: 549.9℃Crucial stress: 7.45mpaIgnition temperature: 516℃Explosion limit (v/v): 15.3%Lower explosion restrict (v/v): 1.6 %Property: White needle crystal, discolored through light, with special odor.Solubility: Soluble in hot water, soluble in bloodless water, ethanol and ether, slightly soluble in benzene. Packaging, storage, transportation:1: 25kg (internet weight) kraft paper laminated bag, coated with double polyethylene plastic bag.2:
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Physical and chemical properties:Density: 1.328g/cm3Melting point: 172-175℃Boiling point: 286℃Flash point: 141.6Refractive index: 1.612Critical temperature: 549.9℃Critical pressure: 7.45MPaIgnition temperature: 516℃Explosion limit (V/V): 15.3%Lower explosion limit (V/V): 1.6 %Property: white needle crystal, discolored by light, with special odorSolubility: soluble in hot water, soluble in cold water, ethanol and ether, slightly soluble in benzene Packaging, storage, transportation:1: 25KG (net weight) kraft paper laminated bag, lined with double polyethylene plastic bag.2: Store in a cool
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Corn oil antioxidant TBHQ, also known as tert-butylhydroquinone, white crystalline powder with a point of 126.5-128.5 ℃ point of 300 ℃ CAS No.: 1948-33-0, easily soluble in alcohols and waking up to the majority of fats and oils, especially vegetable oils antioxidant function of the most effective.
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Product ApplicationsAntioxidants in soybean oil antioxidant effect in the following order: TBHQ>Vc>VE>Catechin>BHT, of which TBHQ, VE and BHT oil solubility is good, heat does not occur after the colour change, suitable for use as a high-grade soybean oil antioxidant.
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Fully dissolve and evenly disperse TBHQ in oil, otherwise it will affect the antioxidant effect.Some organic acids and their derivatives can enhance the activity of TBHQ. It is better to mix it with 0010.02% citric acid.This product cannot be mixed with PG (Propyl Gallate) for use. Avoid using this product under strong alkaline conditions.Oil is one of the basic nutrients in human diet, and most foods contain abundant oil. It can be said that human health cannot do without oil, and the quality and safety of oil are closely related to human health.
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Although some people don't know about the Antioxidant (oil-soluble) TBHQ , Antioxidant (oil-soluble) TBHQappears in all corners of our lives and quietly improves our quality of life.Product Parameters:Molecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0TBHQ is a highly effective and safe food antioxidant, which has been approved for use in more than one hundred countries and regions around the world, including Europe, America, Asia, Australia, Africa, etc.
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In the United States and China, the maximum allowable dosage of TBHQ in food is 200ppm,At present, the production of tert butyl hydroquinone both domestically and internationally adopts the tert butylation method of hydroquinone, as shown in Figure 2. According to different classifications of alkylation reagents.Both domestic and foreign patent literature have reported this process, such as using toluene or xylene as solvents, the selectivity and yield of this reaction are relatively ideal.
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In view of the advantages of TBHQ and BHT, in recent years, BHT and TBHQ have become widely used antioxidants in fats and oil-rich foods . It should be pointed out that TBHQ and BHT have small molecular weights, are volatile and easy to sublimate, and under heating conditions, both volatilization and depletion are relatively fast, and the antioxidant performance will be generated through a series of complex redox reactions to produce the corresponding transformation products.
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The pumping method injects the TBHQ concentrated solution prepared by the seed method into a pipeline with a fixed flow rate and flow rate of fat or oil that needs to be stable at a specified proportion through a stainless steel quantitative pump.
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The antioxidant effect of this product is very ideal, 5-7 times stronger than BHA, BHT, and PG.
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With the development of farming and pet industry, the market demand for feed is increasing day by day, feed antioxidant TBHQ into the people's vision.1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0The experimental results show that adding 002% TBHQ to oil can increase the antioxidant stability of the tested oil by 2-5 times, thus extending the shelf life of oil based foods compared to adding traditional antioxidants; And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination
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There are two types of antioxidants, one is chemical synthesized and the other is natural antioxidants.       Chemical synthesis, such as BHT, BHQ, TBHQ, ethoxyquinoline, PE, etc., these are considered to be called chemical synthesis of antioxidants, these antioxidants have been banned in Europe, that in China and the United States, is the amount of additive per kilogram can not be greater than 0.2, these chemical synthesis of antioxidants, it is true that there is now some controversy, but the antioxidant effect is relatively good.
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1.Product ParametersMolecular formula: C10H14O2Molecular weight: 166.22CAS No.: 1948-33-0Antioxidant TBHQ is a highly effective and safe food antioxidant, which has been approved for use in more than one hundred countries and regions around the world, including Europe, America, Asia, Australia, Africa, etc.
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It can be seen that various antioxidants have significant antioxidant effects, with the order of advantages and disadvantages being TBHQ>PG>BHA>BHT>tocopherol.And the antioxidant effect increases with the increase of the addition amount; The use of a small amount of synergist in combination with TBHQ can have a synergistic effect on antioxidant activity and enhance its antioxidant effect.Especially in areas with high room temperature, such as some southern regions of China, the sourness and flavor of instant noodles have become a hot topic of concern for instant noodle production e
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Relate News
Shandong BEST Each delivers high quality synthetic rubber antioxidant (DTBHQ) to Weifang efficiently, helping the rubber industry to upgrade again. Recently, Shandong Best Best Food Technology Co., Ltd. successfully delivered a batch of high-quality synthetic rubber antioxidant (DTBHQ) to Weifang on time, and this efficient and accurate logistics service once again demonstrated Best's excellent ability in product quality and logistics efficiency. Since its establishment in 2015, Shandong BEST Food Technology Co., Ltd.
Chinese nameHydroquinoneForeign nameHydroquinoneAliasHydroquinone, 1,4-benzenediolChemical formulaC6H6O2Molecular weight110.111CAS registration number123-31-9EINECS number204-617-8Melting point172 to 175 °CBoiling point286 °CDensity1.328 g/cm³AppearanceWhite crystalline powderFlash point141.6 ℃ApplicationBlack and white developer, anthraquinone dyes, azo dyes, rubber antioxidant, stabilizer and antioxidantSafety descriptionS26; S36/37/39; S61Hazard SymbolsXn; NHazard Descriptionr22; r40; r41; r43; r50; r68UN Dangerous Goods Number2662Soluble in alcohols and ethers, soluble in water, slightly s
In modern society, shelf life is one of the key factors for food safety. Therefore, in order to extend the shelf life of food and ensure its stable quality, many food manufacturers use TBHQ, a synthetic antioxidant, which has the advantages of antioxidant, preservative and shelf life extension, and is widely used in various food products.In the potato chip industry, TBHQ is a commonly used food additive. During the production of potato chips, the surface of potato chips will oxidize when exposed to the environmental atmosphere, thus affecting their taste and texture.
TBHQ, also known as Tert-Butylhydroquinone, is a food additive that is a synthetic chemical widely used in the food industry to extend the shelf life of foods and prevent oxidation.TBHQ is produced by reacting hydroquinone with tert-butyl alcohol to produce TBHQ, a process that uses advanced technology and strict controls to ensure the high purity and stability of the product.The multiple uses of TBHQ in the food industry are mainly for preventing the oxidation of fats and oils during food processing and storage, thus extending the shelf life of food products.
TBHQ is a new synthetic antioxidant with good antioxidant effect, especially for vegetable oil antioxidant, has a very good anti-corrosion effect, is internationally recognized as one of the best food antioxidants.Benefits of using TBHQ in food:Good antioxidant effect, added to food can prevent food spoilage and odor, and well prolong the shelf life of food; in addition, it has anti-mold and anti-bacterial effects that other antioxidants do not have, and can effectively inhibit the growth of bacteria such as Bacillus subtilis, Staphylococcus aureus, Escherichia coli and other microorganisms su
Shandong Best Each Food Technology Co., Ltd. (hereinafter referred to as “Best each”)has successfully completed the shipment of a batch of high-quality food products to the beautiful coastal city of Lianyungang.
Application cases of TBHQEdible oils and fats: Adding TBHQ to edible oils and fats can effectively slow down the rancidity process and prolong the shelf life of food. In practical application, TBHQ is usually added directly into oils and fats in the form of powder or liquid, and the usage amount is usually 0.01% to 0.02%.Meat products: Adding TBHQ to meat products can extend shelf life and prevent bacterial contamination and oxidative deterioration.
Terbutylhydroquinone has good antioxidant effect. It has no bad taste and odor when added to any oil and oil-containing food. Good oil solubility, low toxicity, low dosage, it belongs to safe A(1) products, the antioxidant capacity is greater than propyl gallate (PG), 2,6-di-tert-butyl-p-cresol (BHT), tert-butyl-p-hydroxyanisole (BHA); added to food without bad odor.
Precautions for use 1. The amount and proportion of terbutylhydroquinone used should be strictly controlled and should not exceed the maximum amount specified.2. Terbutylhydroquinone should be used in acidic medium, avoid mixing with alkaline substances.3. Terbutylhydroquinone should be stored in a cool and dry place, avoiding direct sunlight and high temperature environment.4. butylhydroquinone should be stored in stainless steel or glassware when in direct contact with food, avoid using plastic containers.5.
6. Safety EvaluationThe safety evaluation of TBHQ mainly includes toxicological evaluation and safety assessment. According to the results of many studies at home and abroad, the acute toxicity of TBHQ is low, and the oral LD50 of mice is 9.31g/kgbw, which belongs to the low toxicity category. In terms of safety assessment, the International Expert Committee on Food Additives (ECFA) considered TBHQ to be safe within the specified range of use.
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